I think to say the book has a heavy focus on frequentist statistics is a little misleading. Jaynes discusses a lot of frequentist methods but the emphasis is on doing so from a very Bayesian point of view.
He uses Bayesian methods in some cases, and non-Bayesian method in others. For instance on page 1412 he describes a problem for which Bayesian methods are "not appropriate."
http://omega.albany.edu:8008/ETJ-PS/cc14g.ps
This is a bit of an anathema to purist Bayesians like Radford Neal who say that Jaynes Maximum Entropy method is not consistent with Bayesian methods and that it "doesn't make any sense"